On the first day of school, a bucket of water lands on Lilly's head, and she meets two burglars who are about to steal the school computers.

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Lilly, Laurenz, Yeliz, Marie and Karol find diamonds on the Elbe beach , which are hidden inside of cuttlefish. When they have the gemstones examined by an expert, gangsters try to take away the valuable find. The peppercorns are barely able to escape the crooks and flee to Lilly's father, the head of Port Security.

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Laurenz, Yeliz, Lilly, Marie and Karol come on the trail of research by the Kenyan journalist Mado criminals. The criminals sell fake, ineffective drugs to Africa. Mado was hit on the run by the counterfeiters after they had caught him while researching in their warehouse. Lilly and Karol are also surprised at spying.

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The car of Lilly's grandmother is stolen with Lilly's precious cat Harmony in it. Immediately, Lilly drums the peppercorns together. Together, the five set out on a dangerous search for the thieves.

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Yeliz faints in the playground and her friend Lilly finds diet pills with her. When Laurenz examines these, the pills turn out to be illegal and extremely harmful to health.

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Laurenz witnesses Moritz being beaten and filmed by older students. A clear case of "happy slapping": The perpetrators film their victims, to later specify on the Internet.

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Laurenz should get for his mother 500 euros at the ATM. However, he does not notice that a rogue couple using a hidden micro-camera and a reader spied on the account data of the debit card. The next day, Rika accuses her son of having taken more money than agreed from her account. Laurenz wants to find the true thieves with the other peppercorns.

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Shortly before the 125th anniversary celebration in Teekontor Krogmann, the family becomes the victim of blackmail.

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Pia, the director's daughter, quarrels with Therese from Togo. When Lilly and Yeliz visit Therese for their birthday, they find an empty apartment. From a neighbor they learn that Therese and her mother left the apartment in a hurry, shortly after Pia paid them a visit. What's going on there?

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The peppercorns have to move out of their headquarters. Laurenz's parents want to sell the warehouse floor in the Speicherstadt to the investor Mr. Meyer. The peppercorns find out that Meyer is the boss of a far-right youth organization. Yeliz gets caught trying to film the troupe. But the peppercorns do not give up.

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First the letterbox explodes, into which Laurenz and Marie have just thrown the envelope with signatures against animal experiments. Then Laurenz also finds out that his best friend Karol has a crush on his girlfriend Yeliz. Laurenz swears that he will bring down the bombers. Alone, without the others. He puts himself and all peppercorns before their greatest challenge.

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Karol gets an old Madonna painting from his uncle Pawel. Although Pastor Leo blesses the picture, Karol is visibly unimpressed. He prefers to sell it for a small amount to a junk dealer to finally afford his coveted game terminal. The peppercorns meanwhile find out the true value of the "Black Madonna" on the Internet, which is around 20,000 euros. For Karol it is clear: he has to have the picture back.

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Lilly is angry because her father wants to move away, and leaves. But she is being followed by a girl gang who is after her new jacket.

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